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How I Recondition Cells

Discussion in 'Gen 2 Prius Main Forum' started by tracy ing, Jun 19, 2022.

  1. JohnPrius3005

    JohnPrius3005 Active Member

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    hahahaha
     
  2. tracy ing

    tracy ing Active Member

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  3. tracy ing

    tracy ing Active Member

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    I have only ever written BAD on two modules, this is one of them, it did not work at all.
    It has been filled with water, somewhat drained after soaking overnight, and here is where it is now
    Put in 6 amp hours at 6.5 amp load got out 4.98 at 6.5 amp load
    83% charge efficiency, not terrible.


     
    #183 tracy ing, Jul 31, 2022
    Last edited: Aug 1, 2022
  4. tracy ing

    tracy ing Active Member

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    Red 6 Ah in @ 6.5 amps
    Provided 4.976 Ah to 6 volts @ 6.5 amp load
    82.9% Charge Efficiency

    Green 6.050 Ah in @ 6.5 amps followed by 2.150 Ah in @ 2.5 amps until EOC reached. 8.2 amps in
    Provided 5.798 Ah to 6 volts @ 6.5 amp load
    70% Charge Efficiency
    4 min volts and resistance
    7.343 volts 7.65 mU (both are too high)

    bad.jpg
     
    #184 tracy ing, Aug 1, 2022
    Last edited: Aug 1, 2022
  5. tracy ing

    tracy ing Active Member

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    Red is the worst and best of my previous modules from herein

    Green is worst and best for the BAD module that was filled with water and reconditioned

    bad3.jpg
     
  6. tracy ing

    tracy ing Active Member

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    The BAD re-hydrated module compared to a lot of other modules

    SEALING MODULE
    This is EASY to do, we have PROVED that my threaded brass insert (NEVER USE BRASS IN NIMH) will withstand the 90 PSI where the vent system activates, and it is merely threaded in with a lot of teflon tape to take up space in the threads and tighten it up.

    To seal back up, ROUND PLASTIC ROD that has an sae pipe thread DIE used on it to create THREADS and some of my 3600 psi plastic weld glue. There is little doubt it will be stronger than the original case plastic and will hold just fine. Thread the rod, cut a piece about 3/8 inch long, run a dremel on it to make a slot for a regular screwdriver, and you have a threaded cap.

    If needed, the cap can be drilled out using the same size drill, re-thread and re-cut a new cap, re-water, insert new cap.

    Mr. LOL

    bad5.jpg
     
    #186 tracy ing, Aug 1, 2022
    Last edited: Aug 1, 2022
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  7. alftoy

    alftoy Senior Member

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    Seems Albert had better luck reinventing the wheel.

    Perfect module resealing tutorial, for the rehydrating process. | PriusChat

    Lol Ozmat
    "I didn't waste quite enough of my life on it last time"
     
  8. tracy ing

    tracy ing Active Member

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    #188 tracy ing, Aug 1, 2022
    Last edited: Aug 1, 2022
  9. alftoy

    alftoy Senior Member

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    Yes, round, what else could they be.
     
    #189 alftoy, Aug 1, 2022
    Last edited: Aug 1, 2022
  10. tracy ing

    tracy ing Active Member

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    Did another recharge, 2 amps until it detected end of charge, 8.408 amps in, almost exactly the same discharge graph, picked up a little Ah over the last run.

    Provided 5.898 Ah to 6 volts @ 6.5 amp load ( 1/10 Ah increase)
    70.1% Charge Efficiency

    Next ???

    Let's drain it, and fill it with a 30% KOH mixture and repeat the process

    P.S. I just looked and found a very faint sharpy note i made on this module 1.8
    So it was marked BAD cause all I could get out of it a few years ago was 1.8 Ah.
    Now it's close to 6 Ah.
     
    #190 tracy ing, Aug 1, 2022
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  11. tracy ing

    tracy ing Active Member

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  12. Prius92

    Prius92 Active Member

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  13. JohnPrius3005

    JohnPrius3005 Active Member

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    At least you guys are chilling out with a little humor!!

    much better than constant sniping
     
  14. tracy ing

    tracy ing Active Member

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    lol pretty sure that's canada
     
  15. tracy ing

    tracy ing Active Member

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    constant sniping
    that's rich
    go reread that past 10 pages
     
  16. JohnPrius3005

    JohnPrius3005 Active Member

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    I meant constant sniping AT you! You're doing all the hard work and interesting experiments. Others were doing little else but finding fault!
     
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  17. alftoy

    alftoy Senior Member

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    Lol, pretty sure?
     
  18. tracy ing

    tracy ing Active Member

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    There was 9 ml of water in the vent hose, not a lot, this includes what "jumped out" under charge and what was "dumped out" by my lifting and rotating the entire battery assembly for that purpose. That 9 ml represented about 8 inches in length in the drain capture tubing, 3/8 inch inside diameter.

    Upon removal of the module from the pack, a further 10 ml was evacuated by turning the module upside down and shaking it like a paint can in a sink with running water for 30 seconds, the liquid escaping was a dark almost black slurry.

    Excess liquid must be removed or it will take up volume normally reserved for the end of charge gassing and pressurization processes.


    IMG_20220802_213837.jpg
     
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  19. tracy ing

    tracy ing Active Member

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    Seems there is a lot of confusion on how to read these measurements, as well as what are good bad measurements.

    "A standard Prius with a single NiMh battery pack will usually show about 0.25 to 0.29 ohms."
    Quoted from a source with a proven knowledge base.

    There are 28 modules
    0.25 / 28 = 0.00893 ohms PER module (8.93 mU)
    0.29 / 28 = 0.01035 ohms PER module (10.35 mU)

    The prius monitors at the level of TWO modules
    0.00893 x 2 = 0.01786 ohms PER monitored module pair (17.86 mU) or 0.018 in techstream
    0.01035 x 2 = 0.02070 ohms PER monitored module pair (20.7 mU) or 0.021 in techstream

    Resistance goes up with heat, upon placing the prius in service in the morning, these resistance numbers WILL go up, in minutes.

    Refer to page 1 of this post and you can see that over 6 miles the resistance increased from 0.020 to 0.021 to 0.024 to 0.026

    Thats a range of 0.010 (cold) to 0.013 (warm) PER MODULE

    A reading of 0.001 (one / one thousandth) is one mU (little m) or milliohm or thousandth of an ohm

    A reading of 0.024 is 24 mU or twenty four / one thousandths of an ohm

    My BENCH tests show readings of 6.4 mU to 7.2 mU as cells are cycled with some spikes in the 10.0 mu range
    These are
    0.064 to 0.072 and 0.10 ohms

    Once installed and placed in use I expect these to increase to the low 20's as reported by techstream (maybe high teens).

    When I see techstream reporting ohms as 0.030 or higher I am looking at modules that may need intervention OR A CLOGGED UP FAN, check the temps in techstream

    This was from an EXTREMELY CLEAN car, 2008, cleaned 2022, was showing high heat and high resistance on a freshly rebuilt pack during test drive. The car was one owner, basically, and operated in and around a university at a major inner city.

    Spray it with windex or 409, hold under faucet in sink, flush it out clean.

    IMG_20220803_021121_01.jpg

    IMG_20220803_021134_01.jpg
     
    #199 tracy ing, Aug 3, 2022
    Last edited: Aug 3, 2022
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  20. tracy ing

    tracy ing Active Member

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    Understanding why reconditioning modules and pulling out low performers (low Ah) helps to somewhat restore the car and its mileage, as well as make it even a car not a doorstop.

    shrinkage.jpg

    "during half-hour exploitation, the battery’s level of charge has varied from 41% to 75%, which
    is narrower scope than the information announced by the car’s manufacturer
    ,"

    International Automotive Conference (KONMOT2018)
    IOP Conf. Series: Materials Science and Engineering 421 (2018) 022041
    IOP Publishing
    doi:10.1088/1757-899X/421/2/022041


    That's only 2.2 Ah on a good 6.5 Ah module
    Using 5 Ah modules would, at best, result in 1.7 Ah but probably much less as the low-end and high-end voltage areas both exhibit a widening that intrudes on, and shrinks (by BMS decision), the Prius working area increasing the number and frequency of charge discharge cycling

    One might think it is a wash, that running 3 minutes at idle with ac on versus 2 doesnt add up to any loss, but the increased charging frequency is the loss, due to charge efficiency of 80 to 90 percent creating a LOSS of 10 to 20%, less frequent charging (better battery) saved fuel in the ac idle test.
     
    #200 tracy ing, Aug 3, 2022
    Last edited: Aug 3, 2022
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