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Charge/discharge efficiency for Lithium-ion polymer battery is quoted at 99.8%. en.wikipedia.org/wiki/Lithium-ion_polymer_battery I'd say...
Bit of mathematics: kWh: 3.66 miles: 14 km: 22.53 (=miles*1.609344) (kWh*1000/km=) Prius PHEV consumption is 162.44 Wh/km (or 261 Wh/mile)...