Clarification on maintenance items

You can get a maintenance schedule at Toyota.com/owner
Engine coolant and some recommend brake fluid.
Don’t overlook egr circuit cleaning, very important at your mileage

 

Things that I would change at your mileage/age:
Engine coolant
Inverter coolant
Transmission fluid
Brake fluid
Spark plugs
Clean EGR circuit

As far as the headlights go I changed ours out with LED and now we can actually see more than 15 feet in front of us at night lol

 

Reading between the lines, sounds like you intend to DIY all these? Which is good; just stay on your toes, research each service. There’s various links in my signature (on a phone turn it landscape to see signatures(.

Using @Andy Pants laundry list, some related repair manual excerpts attached (note, these are from the Gen 3 hatchback repair manual, but I believe almost 100% applicable to the Prius v as well).

Also, if you haven't found it already, pinned at the top of the Gen 3 Prius Maintenance Forum, there's a thread that rounds up @NutzAboutBolts maintenance videos. They're mostly spot-on, with a few exceptions:

Nutz About Bolts Prius Maintenance Videos | PriusChat

Exceptions:

1. Spark plug torque spec is 15 lb/ft, with clean/dry threads, contrary to video (note, this video is excellent, showing the sand-pounding amount of wrenching, just to get to the spark plugs.
2. Hybrid battery fan cleaning does NOT require rear seat removal, contrary to video: there is one bolt behind the seat, and it can be accessed with an extension, through the gap between seat and back)

Also attached, spreadsheet/pdf format summary of the Toyota USA maintenance schedule. I've stuck to the book with this. It does not mention some items, brake fluid change and transaxle fluid change in particular. That's not to say they're not worthwhile; I'm just trying to make a readible-at-a-glance summary of the official Toyota schedule. Note too, it's for Gen 3 Prius hatchback, but as far as I know, identical to the Prius v schedule.

I'd second the need for EGR (Exhaust Gas Recirculation) cleaning. It's new to gen 3 (and the Prius v), and in hindsight woefully underdesigned and tested, prone to clog up with carbon, and in my opinion, the main cause for head gasket failures that are rife with the gen 3 (and v). Optimum would be to clean the full system, including the intake manifold (has EGR passages) every 50k miles.

Can't recall if it's been mentioned above, but the 3rd gen water pump (aka engine coolant pump) has proven prone to fail, relatively slowly and without a lot of warning, "somewhere after" 100k miles. The most prudent course I think would be to replace it every 100K miles. Slightly more risky, every 150K. I would change the adjacent thermostat as well. There have been counterfeit pumps, so be careful. Toyota's pumps are made by Aisin, and when not being sold by dealership have Aisin part no WPT-190. If you can find a genuine one of those it should be equal to the Toyota branded pump, and cheaper. I'd recommend Amayama as a source for these. I don't know conclusively, but the few $100's of things I've bought from them so far have been as advertised.