Re-hydrating the battery modules.

Discussion in 'Gen 2 Prius Technical Discussion' started by Britprius, May 6, 2015.

  1. ChapmanF

    ChapmanF Senior Member

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    When done on a car's cooling system, it's usually done through just one hole. A connector with a 2 or 3 position valve is stuck on the filler neck, the valve is turned to the vacuum source until a good vacuum* is pulled. Valve is turned to the 'neither' position to see if the vacuum holds, then turned to the hose running from the coolant jug, and the coolant gets slurped in.

    -Chap

    * where "good vacuum" is sort of relative ... A/C shops need a motorized pump that can draw within a few microns of absolutely no air; cooling-system tools usually use a shop-air venturi capable of drawing maybe 27 inches of mercury or so.
     
  2. royfrontenac

    royfrontenac Active Member

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    Yes Chap you are right, only one hole would be needed - when I pull a vacuum with my motorized pump on my car's AC I only attach to the connector on the low side of the system.

    My concern might be the amount of vacuum to pull so as to not collapse the cell inward. (using my air conditioning motorized vacuum pump). The hand pump that I use to pull a small vacuum to test vacuum operated valves might do the job using a 3 way valve to direct fluid into the cell.

    To illustrate the power of vacuum, here is a true story.

    I worked in a shop that filled large (very high 13.8 KV voltage) transformers
    (10 ftx10ftx10ft) with oil under vacuum. The transformer tanks were made with very heavy plate steel and you would pull a vacuum to draw moisture out of the electrical windings before filling with oil. We had a round tank about 15 foot long and 5 ft in diameter that we would pump the oil from the transformer into temporarily while doing a repair inside the transformer. One day we pulled a vacuum on the empty big round tank to prepare it for an oil transfer and forgot to shut off the pump - we heard a very big bang and found the big round tank buckled in the middle like a pop can that had been squeezed in half.Scared the hell out of us, we thought the shop had blown up.

    Roy from Canada
     
  3. Britprius

    Britprius Senior Member

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    It is important that the cells are not filled, and have adequate air space at the top. If this is not allowed for there is little or no room for any compression to take place when the cells gas causing the pressure to rise very quickly opening the pressure release valve, and ejecting the corrosive electrolyte.

    John (Britprius)

    Roy you could use grey resin screws bonded in with plumbers plastic pipe weld. Then cut off the screw heads with a craft knife or wood chisel. This would make the work all but invisible.

    John (Britprius)

    Roy the powder you are seing is the crystaline form of the KOH/NaOH chemical. Any areas between the cell plates that have dried out like that will cause a number of problems:-
    The dried area will no longer have any chemical reaction with the cell plates meaning loss of capacity.
    The same area will have a high resistance between the cell plates raising the internal resistance.
    Any areas still in working condition will carry extra current causing that area to heat up, and possibly melt the plate seperaters, and dry the surrounding area of plate even more.

    Adding a non sarurated solution of electrolyte desolves the crystals putting them back to use, and increases the strength of the added solution to compensate for any loss of chemical through leakage or via the vent system.
    This is the reason why I did not use a full saturated solution for re-hydrating. We do not want an elctolyte that will not stay in solution, but need a solution of enough strength to keep cell resistance low.

    John (Britprius)

    It is by no means certain that the vent relief valves on the gen2 modules are any better or different to the gen1 versions. Maybe someone with some spare gen2 modules could test one to find out the initial release pressure. This could be a somewhat hazardous passtime. Alternatively anyone with spare gen2 modules could send me some for further research. (A very blunt way of trying to scroung modules):whistle:.

    John (Britprius)
     
    #23 Britprius, May 7, 2015
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  4. royfrontenac

    royfrontenac Active Member

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    Good idea about resin screws.
    The level in the modules must originally been above the level of the terminal screws,on the inside of the module the terminal is a button that touches the top of the cover - for them to leak the level must have been near the top - what gap would you think is appropriate to leave at the top. I have cut one very close to the top so I could fill a chamber with water and measure the volume when the level is near the top and give you my result if that would help.

    Roy
     
  5. Britprius

    Britprius Senior Member

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    I would not fill the void above the plates in the cells more than 50%, and I think idealy 25 to 30% would be the level to achive. As long as all the plates are covered with fluid the cell will operate to it's full capacity. Adding more fluid does give an edge agaist future loss of the water content, but at the risk of the electrolyte becoming over saturated, and crystals forming as the consentration grows.
    The alternative to cutting a module to get it's capacty would be to drill above one cell and fill it with fluid. Then draw off the fluid with a hypodermic reading the amount able to be drawn off on the scale of the hypodermic. The needle would need a short plastic tube fitted on the end to stop it shorting out the cell when it touches the top of the plates.

    John (Britprius)
     
  6. royfrontenac

    royfrontenac Active Member

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    25 to 35% would leave the level below the battery terminal so the possibility of leaking would be low.
    Roy


    John- I have a module cut off right at the top - exposing the 6 cells. The cells are bone dry - on each side of the battery in each cell is a space about 1/16 in wide that will hold a bit of solution unless the plates expand when hydrated with the new solution.

    Roy
     
    #26 royfrontenac, May 7, 2015
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  7. Britprius

    Britprius Senior Member

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    The electrolyte has a strong ability to creep. It is one of the basic ingreediants for making soap. If you get it on your fingers it turns any fat deposites there to soap making it feel very slippery.

    John (Britprius)
     
  8. royfrontenac

    royfrontenac Active Member

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    Will try that

    Roy

    Putting a new roof on my garage so will be busy for a while - will check for messages to-night.

    Roy
     
  9. Britprius

    Britprius Senior Member

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    I have drawings for the modules and noted this. With the method of filling I am using half of that void either side would be filled with the module laid on it's side. The area above the plates would be filled to 50% level, and I calculated when the module is stood upright the rest of the void at the sides would be filled leaving the top of the cell about 25 to 30% full.

    John (Britprius)

    Roy.
    If the module you have cut the top off is otherwise intact try topping it up just above the plates with distilled water even tap water would do for this experiment, and doing some charge discharge cycles. Charge to at least 9000 mah to get the module warm. This will help dissolve crystals between the cell plates. Discharge down to 5.4 volts. The module will not require clamping. It would be very rewarding to see what capacity it gains, and it's internal resistance. This may also answer the question on if any chemical needs to be added, and go some way towards an independent validation of the results I am seeing

    John (Britprius)
     
    #29 Britprius, May 7, 2015
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  10. MTL_hihy

    MTL_hihy Active Member

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    Roy, any chance you could post a pic because you know the old saying.......

    Very curious about this experimenting and would love to try something similar myself.
     
  11. Britprius

    Britprius Senior Member

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    MTL would the drawings be of any interest.

    John (Britprius)
     
  12. royfrontenac

    royfrontenac Active Member

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    I will try but my skills in the computer area are poor and I may not suceed.
    Roy
     
  13. ChapmanF

    ChapmanF Senior Member

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    I'm thinking the situation is different enough to allay that concern. The modules are built to be under enough compression to hold their shape with internal pressures to +120 psi or more. With the right compressors you can get positive pressures as high as you want, but for some reason nobody ever manages to pull more vacuum than about -14.7 psi no matter what kind of pump they use. :) That probably represents around 300 pounds of inward force on the wide flat sides of the module, which I expect is well under what they normally see from the compression plates in the battery case ... and they're not empty tanks, they have plenty of internal structure to resist collapse.

    Your empty round tank had a surface area around 39,574 square inches ... pull that down to -14 pounds per square inch, and it's feeling a lot of pounds.

    Here's what I'm vaguely thinking (altogether untested, of course):
    1. Build a battery rotisserie. Copy the one in your crazy uncle's garage full of classic car restorations, only scaled down to the size of a traction battery.
    2. With the battery on the rotisserie up-side-up, make one small 'ole in the top of a module and insert the (snugly-fitting, vacuum-tight) fill proboscis.
    3. Open valve to vacuum source until module is maximally evacuated. Close that valve.
    4. Spin rotisserie up-side-down. Open valve to jug of (water or weak solution) located at or above rotisserie height, allowing fluid in to fill module. Close that valve. At this point the module is probably full or near-full.
    5. Open a valve to a clear evacuable container, located below the rotisserie, marked for the desired volume of fluid to draw back out of the module, leaving proper space for expansion. Six cell volumes should equalize as the module is upside-down with the intercell openings at the bottom.
    6. Close that valve, spin back right-side-up and remove the proboscis. Air will enter to fill the expansion space. Drive in the sealing screw.
    Agreed. What seems to be certain is that the Gen 2 terminal seals are better than the Gen 1 versions - only the Gen 1 versions required a service campaign to inject sealant between all the positive terminals and the bus bars. There was an old "Murphy's law corollary" that said any expensive semiconductor downstream of a fuse would protect the fuse by blowing first. That seems to be exactly what Gen 1 terminal seals would do to protect the relief valve. Maybe if the relief valve is exercised, though, and brought back to an 80 psi operating threshold, it would be better? No sé.

    For that to work, I guess it would have to be possible to pressurize the module to the point where the relief valve unsticks, even if that is above where the terminal seeps, and it would have to be true that breaching the terminal seal that way once does not leave it permanently compromised. I don't have any evidence one way or another on that either.

    -Chap
     
    #33 ChapmanF, May 7, 2015
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  14. royfrontenac

    royfrontenac Active Member

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    Dont you think drilling 6 holes and letting them fill by gravity would be a lot faster and easier and could be done without removing the battery from the car. However I like doing things the hard way and will probably byild a spit to turn the battery on

    Roy
     
  15. Patrick Wong

    Patrick Wong DIY Enthusiast

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    6 holes * 38 Classic modules = 228 possible places to leak
     
  16. royfrontenac

    royfrontenac Active Member

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    Yes I think you are right.

    Maybe be better to pull a vacuum after all.

    Roy
     
    #36 royfrontenac, May 7, 2015
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  17. ChapmanF

    ChapmanF Senior Member

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    Do you guys see any indication (a lot of plastic parts have a code stamped in somewhere) of what kind of resin the module housings are molded from?-Chap merged Also, do you have a figure for the resin thickness at the top of the module, where the screws are to be inserted? That should be easy for Roy to get with a cut-off top and a micrometer. John, what was the thread pitch of the screws you used? Did you tap the holes in a separate step, using a thread-cutting tap? Or a thread-rolling tap? Or just use a self-tapping (or a thread-rolling) screw? Did you determine what seemed to be a safe limit to tightening torque?

    -Chap
     
    #37 ChapmanF, May 7, 2015
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  18. Britprius

    Britprius Senior Member

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    The modules (gen1) seem to have a top thickness of about 6mm (1/4 inch), but was difficult to measure accurately down a hole only 39/1000 of an inch in diameter.
    The thread pitch of the screws used was 0.3mm or 70 tpi. I tapped the holes directly with a number 3 finishing tap to avoid any possibility of a tapered tap touching the cell plates. The screws were a tight binding fit in the threaded holes requiring steady turning force from a Phillips screw driver. There seemed little risk of stripping the plastic thread with the limited amount of torque able to be applied by such a small contact area of the small screw driver that would fit the screws. I have the strong suspicion that even if the screws were backed out of the holes a couple of turns they would still not leak.
    I believe you could just drive the screws directly into the drilled hole without tapping them, and perhaps getting an even greater sealing effect. My difficulty was the limited number of modules I had to work with, and the requirement to be able to complete the tests with only 2 module.
    Roy may possibly be able to help more in this area by trying different methods of fitting the screws, and type of screws in the top of the module he has cut off.
    However I must reiterate sealing the module with these very small screws does not seem problematic bearing in mind I did not use any type of sealant, and the test pressure was double the relief valve pressure.

    John (Britprius)
     
  19. royfrontenac

    royfrontenac Active Member

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    Here are some pictures and dimensions of the Gen 2 module with the top cut off.
    The thickness of the top is 11/64 inch (4.4 mm) the total depth from the top of the module to the top of the battery below is 17/32 (13.49 mm).

    This is a correction of a measurement I made in the top of the module --- the thickness of the top is only 2,2 mm thick, I give Alex credit for pointing this error out. My measurement included a lip on the top cover that cannot be seen in the pictures. This points out how small a surface the screw has to seal the cell after hydration. Some sort of flexible sealant may have to be used if leaking eventually occurs when the modules are installed in a working battery. John uses fine thread screws and I used course thread self tapping screws. He has pointed out the fine thread gives a better sealing process and may be all that is needed to prevent leaking. I used self tapping for speed of the work as I did 38 modules with 6 holes each with the battery in place in the car. I later had to seal the screws because of leaks.


    Roy from Canada
     

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    #39 royfrontenac, May 8, 2015
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  20. Britprius

    Britprius Senior Member

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    A possible problem with using the vacuum method is that the cell plates will be put under pressure towards each other something that does not happen even with the modules clamped in the battery case. If dry crystals have formed between the plates these could easily be pushed through the thin separator plates and cause a shorted cell.

    John (Britprius)
    merged
    A useful set of pictures there Roy. Did you read my post #29? It would be really helpful if you could try charging one of the modules with the top removed following the instructions in that post.

    John (Britprius)
     
    #40 Britprius, May 8, 2015
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