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New Solar Technology

Discussion in 'Environmental Discussion' started by FL_Prius_Driver, Jan 26, 2011.

  1. FL_Prius_Driver

    FL_Prius_Driver Senior Member

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    A crew from Cal Tech and ETH (in Switzerland) have tested a rather stunningly good solar technology with two uses.

    It uses concentrated solar to heat a gas reaction chamber. The only thing in the reaction chamber is Sponge Ceria (Metal Oxide) formed into a hollow cylinder. Here is how it works:

    1) Heat Ceria to 1600 C while pumping nitrogen purge gas through the cylinder wall for many minutes. 90 minutes in this case, but dependent on solar, chamber and Ceria engineering. Out comes oxygen and the original nitrogen. Do this till the Ceria runs out of stored oxygen. This occurs as fast as you can pump the cylinder.

    2) Cool down the chamber to 700 degrees (turn off the sun), then pump in water vapor OR carbon dioxide.

    3) Out comes Hydrogen OR Carbon Monoxide. At this lower temperature, ceria strips the oxygen away from the water OR CO2.

    4) Turn the sun back on and go to step 1. Repeat all day long.

    Use the Hydrogen for fuel OR the CO for other further chemical processing.

    If you are paying attention, this is industrial level photosynthesis. A 100% sustainable process that removes CO2 from the air, generates 100% sustainable fuel, and is 100% byproduct clean...no waste products.

    The key is the efficiency. The little test device was a proof of principal that only was 1% efficient, but this was due to the softball size chamber being poorly insulated. The ceria efficiency is around 16% once the chamber losses are eliminated. When scaled to the size of an industrial solar plant, we are talking about a major fuel source. Ceria is the common stuff used to line ovens to make them self cleaning, so that is not a limitation. It takes decades to build big solar plants that could use this technology, but I like the numbers.
     
  2. Tekdeus

    Tekdeus Shifted to Green

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    Good to hear. Solar seems like a solid choice of energy to pursue, given that it isn't going to run out any time soon; it's the essential equivalent of free energy.
     
  3. cit1991

    cit1991 New Member

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    The expensive parts are the mirrors and the tower. Take those and run a water/steam power plant with that energy. Take the electrical power and put it on the grid, thereby backing down a coal-fired power plant. That (net) puts CO2 into the ground as coal.

    I wonder which way saves more CO2?
     
  4. FL_Prius_Driver

    FL_Prius_Driver Senior Member

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    No contest that the best generic use of solar power is to make electricity. However, there will always be niches that can need a energy product other than electricity or are more efficient using solar directly.....just like the optimum solar homes heat hot water directly vs photoelectric heating.

    This struck me as interesting since it captures Carbon directly from the present waste product of burning carbon.
     
  5. franzly

    franzly New Member

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    In 21st century, solar power has already become a small part of daily life. Technology is moving fast to keep up with the renewable revolution. Yet many wonder if small applications will be all solar power is capable of handling. Certainly, the difficulties of large solar plants are many, although many experts continue to insist that the future of solar energy is quite sunny. According to some experts, the sun is our best source of renewable, clean energy. Some estimate that the sun can produce 10,000 times as much energy as the Earth uses at the turn of the 21st century. The future of solar energy depends mostly on how it is applied, rather than whether it would be enough energy to be viable world power source.
     
  6. tripp

    tripp Which it's a 'ybrid, ain't it?

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    reminded me of a stirling engine until the bit about making H. That's pretty cool. It's basically a solar powered syn-gas plant. We could actually make carbon-neutral liquid fuels with this technology. Yes the mirrors are pricey, but standard CSP plants already prove that those costs are pretty easily managed while producing power that not that expensive and will continue to get cheaper. Being able to make liquid fuels with solar power and atmospheric CO2 would be pretty sweet.
     
  7. FL_Prius_Driver

    FL_Prius_Driver Senior Member

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    I would point out that there are two major economic breakpoints fast approaching

    1) Breakpoint one is when a full size solar plant (in the SW USA) can make daytime electricity cheaper than coal plants. I expect we are about 6-12 years away. That's might close. Keep in mind that 6-12 years is less time than from starting a nuke plant to it being on line.

    2) The major breakpoint two is when a power storage technology reaches maturity to store enough to make a solar plant run 24/7. Wild guess that this is 20 years away. Then the environmental issue will be the destruction of the Mojave due to solar power plants.

    So I try to be a forward looking type to see what storage technologies are viable, since that will start the big money shift from coal/nuke/gas to Solar Thermal/Solar Sterling/Solar PV power plants.
     
  8. austingreen

    austingreen Senior Member

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    That may even be today in cali. They have outlawed coal, and do not produce nearly as much energy as they use. If another drought hits, California will again spike the price of natural gas. I doubt unsubsidized economics really work out in much of the rest of the country for sun, but there are other renewable that do. Given the choice Texans are adding wind power as fast as the grid will take it. Household solar with the subsidies also makes economic sense today.

    Storage is not a problem. Like it does with Texas wind, natural gas can even out the power. In California there is plenty of natural gas on line to even out the demand until much larger amounts of solar/wind/biomass are added. The California grid though needs improvement to move power from the good solar sources to the people. That is part of this project, but more grid work also needs to be done.
     
  9. icarus

    icarus Senior Member

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    Plug in hybrids/evs in large numbers become the storage bank for solar and wind. They would allow two way energy transaction. Absorbing excess Pv/wind at times of low demand, selling power back to the gird at times of peak demand,, cutting down on the wasteful idle spinning capacity.

    Icarus
     
  10. hill

    hill High Fiber Member

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    Sadly, coal "costs" are often not reported as costs. Mine injuries and the colateral pollution in just running & decommissioning mines are not taken into consideration
     
  11. FL_Prius_Driver

    FL_Prius_Driver Senior Member

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    I'm not sure that the rest of the country is a "work out" vs. "not work out" break as much as the obvious statement that the economics breakpoints really vary. Florida would be a viable solar state, but only after the SW USA solar construction has lowered capital plant cost significantly. In cloudier states, the PV route may be better suited, but that breakpoint is farther away. It's also essential to point out that low loss, long distance transmission (e.g. viable superconducting lines) would also change the economics significantly even in very remote states.

    Again, I view large scale storage technology as the key to changing solar from being a peaking power source to a prime power source. It's not so much whether the technology exists, it already does....it's when the cost of the technology allows investors to make money investing in prime power solar plants. That's the breakpoint my post was focusing upon.
     
  12. tripp

    tripp Which it's a 'ybrid, ain't it?

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    seems like molten salts are the storage solution for solar thermal plants. They're cheap and very efficient.
     
  13. austingreen

    austingreen Senior Member

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    That seems like a help when we get to much higher levels of solar. I'm not sure we will ever get their in the south west. It seems that with all the natural gas generating capacity, and the ease to turn on an extra turbine in a combined cycle plant, natural gas seems the natural load balance. One problem is the grid for California covers half the nation, and it needs to be improved to drop in Concentrated solar where it makes sense. I don't think we need to add molten salt capabilities in the Mojave.

    In texas gas is used to load balance wind, and we believe this will work up until we get to 30% of the electricity from wind power. There are even political fights on whether wind providers should have to subsidize the ng plants for the changing loads. Texas has its own grid and is improving it with the help of state and federal monies to bring large amounts on line. California must deal with other states and the federal government to get their grid ready more sun and wind.
     
  14. FL_Prius_Driver

    FL_Prius_Driver Senior Member

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    Molten Salts certainly are the best developed technology right now. The others that I'm keeping my eye on are:
    1-The high efficiency MIT colbalt chemistry that allows reversable Water/H2-02 seperation & combining.
    2-Molten Battery Chemistries using liquid electrodes and liquid seperators.

    The key here is that the storage is after the turbine stage, allowing significantly different response times and other side processes. When we start talking about 1% differences in efficiency at the GigaWatt level, that turns out to be very big money....big enough to switch horses....if the horse can run.
     
  15. tripp

    tripp Which it's a 'ybrid, ain't it?

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    Adding storage allows for a higher production factor, which increases profit so as long as the price of the storage is reasonable, it seems like a no brainer to add it.

    Of course, as we move away from coal to more and more NG fired plants we're going to chew up our NG at a faster and faster pace (remember when we had > 600 yrs of coal reserves here in the 1970's and we're down to about 200-250 now, 40 years later). That'll make technologies like CSP w/thermal storage all the more important.
     
  16. austingreen

    austingreen Senior Member

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    No I can't remember:mad:, I seem to be too young for most of the forum. :rolleyes: But I had been reading 100 years for coal. I think it is longer only because we will shift away from it.


    Given the high prices and high ng use in California adding CSP makes perfect sense. I was only adding that in California, they don't need to wait for thermal storage to be cost effective, they have plenty of peak leveling capacity. Other parts of the world can and will use thermal storage. So I'm in agreement with the general sentiment, IMHO california should move faster with CSP even without thermal storage.